Wenza njani uZirconium hloride?

I-Zirconium chloride, kwaziwa njengeI-zirconium (iv) chloride or I-ZRCL4, yindawo eqhelekileyo esetyenziswayo kubume bamashishini ahlukeneyo kunye nophando lwenzululwazi. I-crystalline emhlophe iqinile ngefomula yemolekyuli yeI-ZRCL4kunye nobunzima bemolekyuli ye-233.09 g / mol.I-Zirconium chlorideIsebenza kakhulu kwaye inoluhlu olubanzi lwezicelo, ukusuka kwi-catalysts kunye ne-synthesis synthesis kwimveliso ye-ceramics kunye neeglasi. Kweli nqaku, siya kujonga njaniI-Zirconium chlorideyenziwe.

I-synthesis yeI-Zirconium chloridekubandakanya ukuphendula phakathiI-zirconsium oxideokanye i-ziirconnium ritery kunye ne-hydrogen hloride.I-zirconia (Zro2) Iqhelekile isetyenziswa njengezinto zokuqala ngenxa yokufumaneka kunye nozinzo. Indlela yokuphendula inokwenziwa phambi kwearhente yokunciphisa i-carbon okanye i-hydrogen yokukhuthaza ukuguqulwa kweI-zirconsium oxide inyaniI-Zirconium yentsimbi.

Ekuqaleni,I-zirconiaixutywe ne-arhente yokunciphisa kwaye ibekwe kwinqanawa yokusabela. Irhasi ye-hydrogen chloride irhasi emva koko yaziswa kwinqanawa yokusabela, ebangela ukuba impendulo yenzeke. Indlela yokuphendula inokuba yi-edothermic, oko kuthetha ukuba ikhupha ubushushu, kwaye kufuneka yenziwe phantsi kweemeko ezilawulwayo ukuthintela nayiphi na ingozi. Impendulo phakathiI-zirconsium oxidekwaye i-hydrogen chloride imi ngolu hlobo lulandelayo:

Zro2 + 4HCL → I-ZRCL4 + 2O

Impendulo ihlala iqhutywa kubushushu obuphezulu, ihlala iphakathi kwe-400 ne-600 degrees Celsius, ukuqinisekisa ukuguqulwa ngokupheleleyo kweI-zirconsium oxidekwiI-Zirconium chloride. Ukuphendula okuqhubekayo kude kube konkeI-zirconsium oxideiguqulwe ngokupheleleyoI-zirconium (iv) chloridenamanzi.

Nje ukuba impendulo igqityiwe, umxube ophumkileyo uphelile kwayeI-Zirconium chlorideiqokelelwe. Nangona kunjalo,I-Zirconium chlorideNgokwesiqhelo kukho ifom ye-hydad, okuthetha ukuba iqulethe iimolekyuli zamanzi kwisimo sayo sekristali. UkufumanaI-chirconium ye-chirconium ye-chirconium, i-hydaredI-Zirconium chlorideihlala ishushu okanye i-vacuum yomile ukususa iimolekyuli zamanzi.

Ubunyulu beI-Zirconium chloridekubalulekile kwizicelo ezithile. Ke ngoko, amanyathelo ongezelelweyo okucoca amanqanaba anokufuneka asuse nayiphi na into yokungcola okanye ukufuma. Iindlela eziqhelekileyo zokucoca ziquka ukugqobhoza, i-crystal yokuqhawula kunye nokuhlukanisa. Ezi ndlela zinokukhuphaI-charconium ephezulu ye-chirconium ephezulu, ebaluleke kakhulu kwimizi-mveliso eyahlukeneyo kubandakanywa ne-elektroniki kunye nezicelo zenyukliya.

Ukushwankathela,I-Zirconium chlorideidityaniswe yimpendulo yeI-zirconsium oxidekunye ne-hydrogen chloride. Le mpendulo ifuna iimeko ezilawulwayo kwaye ihlala iqhutywa ngamaqondo obushushu aphezulu. IsiphumoI-Zirconium chlorideihlala ifunyanwa kwifom ye-hydad, ngamanyathelo ongezelelweyo afunekayo ukufumana i-arnocound ye-hlorind chloride. Iindlela zokucoca zinokuqeshwa ukuze zifumane inyuluI-Zirconium chloridekwizicelo ezithile. Ukuveliswa kweI-Zirconium chlorideyinkqubo ebalulekileyo, yenza isetyenziswe ngokubanzi kumashishini ahlukeneyo kunye nophando lwezenzululwazi.