I-zirconium (iv) chloride, kwaziwa njengeI-Zirconium Tetracheride, inefomula ye-moleula zrcl4 kunye nobunzima bemoya ye-233.04. Isetyenziselwa ikakhulu njengokuhlalutya kwe-regentas, i-ornthesic synthests, iiarhente zamanzi, iiarhente zokuntywila
Igama lemveliso:I-Zirconium chloride; I-zirconium Tetracheride isebenze; I-zirconium (iv) chloride
Ubunzima bemolekyuli: 233.04
I-Einecs: 233-058-2
Inqaku lokubilisa: 331 (Ukupheliswa komzimba)
Ukuxinana: 2.8
Ifomula yekhemikhali:I-ZRCL4
I-CAS:I-10026-11-6
Inqaku lokunyibilika: 437
Ukunyibilikisa kwamanzi: Inyibilikiswa emanzini abandayo
1.Iplate
Ipropathi yomzimba kunye neekhemikhali
1. Uhlobo
2. Inqaku lokunyibilika (℃): 437 (2533.3.3.3.33Kpa)
I-3. Inqaku lokubila (℃): 331 (Ukupheliswa kwe)
4. Ukuxinana kwesihlobo (amanzi = 1): 2.80
I-5. Uxinzelelo lwe-vapor olwenziweyo (i-KPA): 0.13 (190 ℃)
6. Uxinzelelo olubalulekileyo (MPA): 5.77
7. Ukuntywila: Ukunyibilika emanzini abandayo, e-Ethanol, kunye ne-ether, i-tolbon eBebne, i-carbon tetrachloride.
Kulula ukufunxa umswakama kunye nokufuma, i-hydroged kwi-hydrogen chloride kunye ne-ziirconium oxynchloride kwi-sumad umoya okanye isisombululo se-aceus, i-equation imi ngolu hlobo lulandelayo:
Uzinzo
1. Uzinzo: uzinzile
2. Izinto ezithintelweyo: Amanzi, amahines, amalahle, i-acids, etter, eKetones
I-3. Iimeko zokuthintela ukuqhagamshela: umoya sudd
I-4. Ingozi ye-Polymermermerazation: enganyanzeliswanga
I-5. Imveliso ye-Delolation: I-chloride
Ukupapashwa
.
.
I-3.synthetic yendlela
I-SIRCONIA NECACLON Carbon emnyama ngokwemilinganiselo ye-molar yomlinganiselo, uxube ngokulinganayo uze ubeke kwisikhephe se-porcelain. Beka isikhephe se-porcelain kwityhubhu ye-porcelain kwaye ubushushu ukuya kwi-500 ℃ kumjelo wegesi ye-chlorine ukuze uhlawulwe. Qokelela imveliso usebenzisa umgibe kubushushu begumbi. Ukujonga ukugqobhoza i-zirconclorride kwi-331 ℃, ityhubhu ye-600mm inge inokusetyenziselwa ukuqikelela kumjelo wegesi ye-hydrogen kwi-chirconide kunye ne-fuloride e-chirconide.
4. Impembelelo kwiNdalo esingqongileyo
Iingozi zeMpilo
Indlela yokuhlasela: Ukuphefumla, Ukungenisa, unxibelelwano lolusu.
Ingozi yezempilo: Ukuphefumla kunokubangela ukucaphukisa ukuphefumla, musa ukuginya. Inokukhathazeka okuqinileyo kwaye kunokubangela ukuba ulusu luvutha kunye nomonakalo wamehlo. Ulawulo lomlomo lunokubangela imvakalelo evuthayo emlonyeni nomqala, isicaphucaphu, ukugabha, izitopu zamanzi, izitulo zegazi, ukuwa kunye nokubuqhoxala.
Iziphumo ezingapheliyo: zibangela igranoma yolusu. Ukucaphukisa kancinci kwiphecana lokuphefumla.
I-Toolotology kunye neNdawo
Ityhefu enobungozi: ld501688mg / kg (ulawulo lwasemthethweni kwiigundane); I-665mg / kg (imouse)
Iimpawu ezinobungozi: Xa ziphantsi kobushushu okanye amanzi, ibola kwaye ikhupha ubushushu, ukukhulula umsi onetyhefu kunye notyesi.
Imveliso (i-Deaculation) Imveliso: I-hydrogen chloride.
Indlela yokubeka i-Laborartor: I-Plasma SpectricCOPY
Ukuzimisela emoyeni: Ukuqokelela isampulu kunye nefilitha, kuyinyibilikise nge-acid, kwaye emva koko uyilinganise nge-atomic age spectroscopyptcopy.
Imigangatho yendalo esingqongileyo: Ulawulo lwezeMpilo noLawulo lwezeMpilo (1974), ixesha lomoya elinomgangatho 5.
Ukuvuza uphendula ngendlela engxamisekileyo
Ukwahlula indawo yokuvuza ivunxiwe, setha imiqondiso yesilumkiso malunga nayo, kwaye ucebise ukuba abasebenzi abanonyango olungxamisekileyo banxibe imaski yerhasi kunye nempahla yokukhusela iikhemikhali. Sukungena ngokuthe ngqo nezambatho ezivuliweyo, phepha uthuli, lungisa isisombululo samanzi ama-5% okanye i-acid, ngokuthe ngcembe i-dumonia ivele, emva koko ilahle. Unokukhawulelana nesixa esikhulu samanzi, kwaye usike amanzi okuhlamba kwinkqubo yamanzi amdaka. Ukuba kukho inani elikhulu lokuvuza, yisuse phantsi kwesikhokelo sabasebenzi bezobugcisa. Indlela yokulahla inkunkuma: Hlanganisa inkunkuma nge-sodium bicarbonate, tshiza ngamanzi ammonia, kwaye wongeze i-ice crity crity. Emva kokuba impendulo iyayeka, ihlambe ngamanzi kumjelo wamanzi amdaka.
Amanyathelo okhuselo
Ukukhusela ukuphefumla: Xa ityhilwe eluthulini, imaski yegesi kufuneka inxibe. Nxiba izixhobo ezinesixhobo sokuphefumla xa kukho imfuneko.
Ukukhuselwa kwamehlo: Ngena i-goggles yokhuseleko lweekhemikhali.
Impahla ekhuselayo: nxiba iimpahla zomsebenzi (zenziwe ngezinto ezichasene ne-anti-slosion).
Ukukhuselwa kwezandla: nxiba iigloves zerabha.
Enye: Emva komsebenzi, thatha ishawa kwaye utshintshe iimpahla. Gcina iimpahla ezingcoliswe ziityhefu ngokwahlukeneyo kwaye zibasebenzise emva kokuhlamba. Gcina imikhwa elungileyo yecocekile.
Amanyathelo okuqala oncedo
UQHAGAMSHELWANO LOKHUSELEKO: Ngokukhawuleza hlamba ngamanzi kangangemizuzu eli-15. Ukuba kukho ukutshisa, kufuna unyango.
Ukunxibelelana ngamehlo: Ngokukhawuleza kuphakamisa ii-eyelid kunye nokugquma ngamanzi ahambayo okanye i-saline yendawo enemizuzu eli-15 ubuncinci.
Ukuphefumla: Khawuleza ususe endaweni yendawo enomoya omtsha. Gcina iphecana lokuphefumla elingaphantsi komhlaba. Yenza ukuphefumla okuphezulu ukuba kukho imfuneko. Funa unyango.
Ukungenisa: Xa isigulana sisaphaphile, sihlambe kwangoko umlomo kwangoko, musa ukuphembana, kwaye usele ubisi okanye iqanda emhlophe. Funa unyango.
Indlela yokucima umlilo: i-foam, ikharbon diokside, isanti, umgubo owomileyo.
I-5.Storage indlela
Gcina kwindawo epholileyo, eyomileyo, kwaye inomileyo yendawo yokuhlala. Hlala kude neentlantsi kunye nemithombo yobushushu. Ukupakishwa kufuneka kutywinwe kwaye kukhuselwe kumswakama. Ifanele igcinwe ngokwahlukeneyo kwii-AIDD, amahin, ilokishi, iindlebe, njl njl. Indawo yogcino kufuneka ixhotywe ngezinto ezifanelekileyo zokuvuza.
I-6 yeChemistry Chemistry yeDatha
I-1. Ixabiso lesalathiso seParamitha ye-hydrophobic (i-xlogp): akukho
I-2. Inani le-hydrogen bond abanikeli: 0
I-3. Inani le-hydrogen ye-hydrogen bod: 0
I-4. Inani leekhemikhali ezihlawulelwayo: 0
5. Inani leTautomers: Akukho
I-6. Imolekyuli ye-toalecy ye-Poleclory Indawo: 0
I-7. Inani leathom enzima: 5
8. Intlawulo yomphezulu: 0
9. Ubunzima: 19.1
I-10. Inani le-isotope atom: 0
11. Chonga inani lamaziko e-Atomic: 0
I-12. Inani lamaziko o-Atomic engaqinisekanga: 0
13. Chonga inani lamaziko emichiza ye-stereo ye-stereo: 0
I-14. Inani leqela lokungaqiniseki ze-stecreocenters: 0
I-15. Inani leeyunithi ze-Coupales: 1
Ixesha lokuposa: I-25-2023